4.8 Article

End-cap exchange of rotaxane by the Tsuji-Trost allylation reaction

Journal

ORGANIC LETTERS
Volume 7, Issue 7, Pages 1199-1202

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol047639i

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Rotaxanes possessing a cinnamyl ester group at the axle terminal were prepared. The terminal end-cap was modified with a bulky malonate ester in excellent yield by the Tsuji-Trost allylation reaction, which was carried out in the presence of a palladium catalyst.

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