Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 347, Issue 5, Pages 609-631Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404232
Keywords
asymmetric catalysis; hydroboration; P,N chiral ligands; P,P chiral ligands; mechanistic studies; rhodium
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Rhodium-catalysed enantioselective hydroboration of olefins is a valuable synthetic transformation, typically employing a chiral catalyst and an achiral borane source. The pertinent chemo-, regio- and enantioselectivity issues of this reaction are discussed. However, the main emphasis of this review is on the evolution of catalytic asymmetric hydroboration. This has primarily relied upon the development and application of chiral bidentate PP and P,N ligands which have exhibited varying degrees of success in this transformation.
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