Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 347, Issue 5, Pages 673-676Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404323
Keywords
aldehydes; chemoselectivity; dithioacetals ketones; protecting groups; ruthenium chloride
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A variety of carbonyl compounds can be easily and rapidly converted to the corresponding cyclic and acylic dithioacetals in the presence of a catalytic amount of ruthenium chloride in acetonitrile at room temperature. Some of the major advantages of this protocol are high chemoselectivity, operational simplicity, very short reaction times, high yields, and also compatibility with other protecting groups.
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