Journal
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
Volume 41, Issue 4, Pages 361-367Publisher
PLEIADES PUBLISHING INC
DOI: 10.1007/s11175-005-0077-0
Keywords
dissociative electron transfer; Anderson model; effects of electron-electron correlations; adiabatic free energy surface
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Adiabatic free energy surfaces for adiabatic electrochemical reactions of dissociative electron transfer are calculated with exact allowance for the effects of electron-electron correlations in a model of an electrode with an infinitely broad conduction band. The role of correlation effects in these reactions is discussed. It is shown that, as in common adiabatic electrochemical reactions of electron transfer, correlation effects play a substantial role and lead to a considerable decrease in the activation free energies.
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