Journal
PHYSICS AND CHEMISTRY OF MINERALS
Volume 32, Issue 1, Pages 40-51Publisher
SPRINGER
DOI: 10.1007/s00269-004-0441-8
Keywords
titanite; rietveld analysis; crystal structure; distortion; zirconium
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Inhomogeneous aggregates of late-stage titanite enriched in Zr have been described recently from post-magmatic parageneses in silica-undersaturated rocks. In the natural samples, simple isovalent substitution of the large Zr (R-[vi](4+) =0.72 angstrom) for Ti (([vi)]R4+ = 0.605 angstrom) is limited to an empirical maximum of 0.25 afu (15.3 wt.% ZrO2). As the natural material is not suitable for crystallographic study, a series of CaTi1-xZrxOSiO4 titanite samples have been synthesized by standard ceramic methods at ambient pressure in air, and their crystal structure determined by Rietveld refinement of laboratory powder X-ray diffraction patterns. All of the synthetic Zr-doped titanite varieties adopt space group A2/a and consist of distorted CaO7 polyhedra together with less distorted (Ti1-xZrx)O-6 octahedra and SiO4 tetrahedra. Cell dimensions and atomic coordinates together with volumes and distortion indices are given for all polyhedra. The empirical limit for Zr substitution in synthetic (F,OH)-free titanite is 0.5 afu (29.6 wt.% ZrO2). The existence of a Zr analogue of titanite in nature is considered to be unlikely.
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