Journal
RUSSIAN CHEMICAL BULLETIN
Volume 54, Issue 4, Pages 1060-1062Publisher
SPRINGER
DOI: 10.1007/s11172-005-0360-y
Keywords
dibenzoyl(methanato)boron difluoride; beta-diketonates; fluorescence; luminescence thermochromism; stacking factor
Categories
Ask authors/readers for more resources
Reversible luminescence thermochromism of dibenzoyl(methanato)boron difluoride was found. A substantial hypsochromic shift of the luminescence band maximum (60 nm) with a temperature decrease from 300 to 77 K was observed, and the luminescence color changed from green to blue. A considerable decrease (by 0.386 angstrom) in the unit cell parameters along the c axis was detected by X-ray diffractometry when the temperature of the crystal decreased from 293 to 123 K. Shortening of the distances between the planes of adjacent molecules (stacking factor) weakens the interaction between the dimers and enhances the monomeric and excimeric luminescence.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available