Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 38, Issue 4, Pages 227-234Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar0401707
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Molecular architectures built of inorganic cyanometalate building blocks provide variegated host structures with several organic guest molecules. The strategies to derive novel structures are presented briefly. The formation of a charge-transfer (CT) complex as the guest inside the cavity and the photochemistry of the CT complexes are discussed. The chemical pressure that the guest experiences inside the cavity is also discussed based on the vibrational spectroscopic results.
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