Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 70, Issue 7, Pages 2594-2597Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo048019y
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A new method for the synthesis of 1,5-diynes, from the reaction of 1,3-dilithiopropyne and propargyl chlorides, was developed. This new methodology was used to prepare (4E,6Z,10Z)-4,6,10-hexadecatrien-1-ol, one of the pheromone components of the cocoa pod borer moth Conopomorpha cramerella, in 51% overall yield.
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