Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 70, Issue 7, Pages 2445-2454Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo048132o
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Various nitro-substituted aryl and heteroaryl iodides undergo an iodine-magnesium exchange reaction when treated with PhMgCl leading to nitro-containing magnesium organometallics. These Grignard reagents display an excellent stability at temperatures below -40 degrees C and do not undergo electron-transfer reactions. They react as expected with various electrophiles.
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