Removal of herbicide paraquat from an aqueous solution by adsorption onto spent and treated diatomaceous earth

A spent diatomaceous earth from the beer brewery has been tentatively activated by sodium hydroxide at about 100 degreesC. The resulting product was used as a novel adsorbent for the adsorption of herbicide paraquat from an aqueous solution in a continuously stirred adsorber and batch flasks, respectively. The results showed that the adsorption process could be well described by the pseudo-second-order reaction model. From the view of the negatively charged surface of diatomaceous earth and cationic property of paraquat, the results were also reasonable to be explained by physical adsorption in the ion-exchange process under the effects of pH and temperature. Further, it was found that the Freundlich model appeared to fit the isotherm data better than the Langmuir model. (C) 2004 Elsevier Ltd. All rights reserved.