Journal
CURRENT ORGANIC CHEMISTRY
Volume 9, Issue 6, Pages 555-563Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1385272053544416
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The account highlights an important approach to supramolecular self-assembly via vector-manipulation at metal centers ranging from Werner-system to Cotton-system coordination compounds. The approach has been successfully employed in the architecture of container molecules like metal analogues of the bowl-shaped calixarenes and metal-linked calixarene-based carcerands and carceplexes. The concepts of metal vector and vector-manipulation at metal centers were further interpreted based upon the stereochemistry and trans- or cis-effect of ligands in the substitution reactions at metal centers.
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