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Fullerene-porphyrin constructs

Journal

ACCOUNTS OF CHEMICAL RESEARCH
Volume 38, Issue 4, Pages 235-242

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ar040168f

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Funding

  1. NIGMS NIH HHS [GM 23851] Funding Source: Medline

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Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element can be used to construct discrete host-guest complexes, as well as ordered arrays of interleaved porphyrins and fullerenes. The fullerene-porphyrin interaction underlies successful chromatographic separations of fullerenes, and there are promising applications in the areas of porous framework solids and photovoltaic devices.

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