4.4 Article

Intramolecular metathesis versus Kharasch reactions using the Grubbs metathesis catalyst: towards catalyst economy

Journal

TETRAHEDRON LETTERS
Volume 46, Issue 14, Pages 2381-2385

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.02.060

Keywords

Grubbs; metathesis; Kharasch; cyclisation; competition; decomposition; stability; ATRC; RCM

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The first generation Grubbs catalyst can promote either ring closing metathesis (RCM) or atom transfer radical cyclisation reactions (ATRC) depending upon the reaction conditions employed. (c) 2005 Elsevier Ltd. All rights reserved.

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