4.2 Article

Catalytic application of sulfonic acid functionalized mesoporous benzene-silica with crystal-like pore wall structure in esterification

Journal

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 230, Issue 1-2, Pages 85-89

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2004.12.010

Keywords

mesoporous benzene-silica; crystal-like pore wall; nation; estrification; sulfonic group functionalization; acidic acid and ethanol

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The first catalytic applications of sulfonic acid-functionalized hydrophobic mesoporous benzene-silica with lamellar pore wall structure are reported. The mesoporous benzene-silica attached with propylsulfonic groups to the crystal-like periodic pore walls exhibited the catalytic activity in the esterification of acetic acid with ethanol. The catalytic results show the higher conversion compared to the commercial Nation-H. (c) 2004 Elsevier B.V. All rights reserved.

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