Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 230, Issue 1-2, Pages 129-133Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2004.12.015
Keywords
pyridinium-based ionic liquids; alkylation Friedel-Crafts; iron chloride; aluminum chloride
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The Friedel-Crafts alkylations of benzene in pyridinium-based ionic liquids (ILs) were investigated. The effects of catalyst-IL composition, reactant composition, quantity of catalyst and reaction temperature on this reaction were studied. The reactions were found to proceed under mild conditions with conversion; a simple product isolation procedure was achieved. The ILs rendered this reaction green characteristics. The ILs could also be recycled and reused as opposed to traditional solvent-catalyst systems. (c) 2004 Elsevier B.V. All rights reserved.
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