Journal
APPLIED PHYSICS LETTERS
Volume 86, Issue 15, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.1901826
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We describe the phosphorescent characteristics of two platinum complexes containing an (NCN)-C-∧-N-∧-coordinating tridentate ligand: platinum(II) 3,5-di(2-pyridyl)toluene chloride [Pt(dpt)Cl] and a newly synthesized platinum(II) 3,5-di (2-pyridyl) toluene phenoxide [Pt(dpt)(oph)], together with the performance of organic light-emitting diodes (OLEDs) prepared with these complexes as phosphors. Films containing each one of the complexes in a 4,4'-N,N'-dicalbazolylbiphenyl (CBP) host showed highly efficient photolurninescence. The fabricated OLEDs exhibited high efficiencies; the maximum external quantum efficiency of the device with Pt(dpt)(oph) phosphor after correction of angular dependence of emission was found to be 16.5%. The luminance half decay time of the Pt(dpt)(oph) device under a constant-current operation was considerably longer than that of the Pt(dpt)Cl device. (C) 2005 American Institute of Physics.
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