Journal
TETRAHEDRON LETTERS
Volume 46, Issue 15, Pages 2581-2584Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.02.080
Keywords
allylic oxidation; unsaturated compounds; bismuth; t-butyl hydroperoxide
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Bismuth(III) salts are efficient catalysts for the selective allylic oxidation using tert-butyl hydroperoxide. BiCl3 is especially effective and can be easily recovered and reused as BiOCl. Using BiCl3/K-10 as catalyst, an increase in the reaction rate was observed. (c) 2005 Elsevier Ltd. All rights reserved.
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