Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 127, Issue 14, Pages 5097-5103Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja042479r
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We report that dendrimer-encapsulated Pd nanoparticles having a diameter of similar to 1.7 nm are effective and general catalysts for coupling aryl halides to organostannanes (the Stille reaction) under mild conditions. The significant results of this study are that the Stille reaction is catalyzed by dendrimer-encapsulated Pd nanoparticles in very good yield, in aqueous solution at 23 degrees C, and using only 0.100 atom % of Pd as catalyst.
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