4.8 Article

Rhodium-catalyzed reaction of thiols with polychloroalkanes in the presence of triethylamine

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ORGANIC LETTERS
Volume 7, Issue 8, Pages 1537-1539

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AMER CHEMICAL SOC
DOI: 10.1021/ol0501673

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[GRAPHICS] RhCl(PPh3)(3) catalyzes a reaction of thiols with polychloroalkanes in the presence of triethylamine. This reaction serves as a convenient new method to produce formaldehyde dithioacetals, ethylenedithioethers, thioformates, and dithlocarbonic esters under mild conditions.

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