Journal
ORGANIC LETTERS
Volume 7, Issue 8, Pages 1661-1663Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0504300
Keywords
-
Categories
Funding
- NIGMS NIH HHS [GM31077] Funding Source: Medline
Ask authors/readers for more resources
Three novel domino reaction processes have been discovered and developed that employ the regioselective and stereoselective [Rh(CO)(2)Cl](2)-catalyzed alkylations of allylic trifluoroacetates with alpha-substituted sodiomalonates followed by an intramolecular Pauson-Khand annulation, a [5 + 2] cycloaddition, or a cycloisomerization. A unique aspect of the methodology is that a single catalyst is used to effect sequential transformations simply by increasing the temperature for the second reaction.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available