Association of trans-[PdCl2(NH=CPh2-kN)2] via intermolecular N-H...Cl hydrogen bonding in the solid state and in solution

The crystal structure of a new complex, trans-[PdCl2-(NH=CPh2-KN)(2)], shows an association of the two mole-cules via intermolecular N-H...Cl hydrogen bonds. The (1) HNMR signal of the N-H hydrogen in CDCl3 changes its position depending on the concentration and temperature of the solution.