Journal
TETRAHEDRON LETTERS
Volume 46, Issue 16, Pages 2903-2906Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.02.135
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The asymmetric reduction of benzophenones multisubstituted at the ortho-positions was achieved via hydrosilylation catalyzed by in situ generated chiral diamine-Zn-diol complexes under mild conditions, wherein polymethylhydrosiloxane (PMHS) served as a safe and inexpensive source of hydride. (c) 2005 Elsevier Ltd. All rights reserved.
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