Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 15, Pages 2014-2016Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b418939f
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Funding
- NIGMS NIH HHS [GM47365] Funding Source: Medline
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While a 1:1 Cu-O-2 adduct is generally unreactive with organic substrates, phosphines displace O-2 via an associative process and added Cu(I) leads to a novel internal ligand oxidation to yield a Cu(II)-o-iminosemiquinone complex.
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