Journal
TETRAHEDRON LETTERS
Volume 46, Issue 17, Pages 3115-3117Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.02.164
Keywords
chiral palladium complexes; fluorination; asymmetric reactions
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The catalytic enantioselective electrophilic fluorination promoted chiral palladium complexes is described. Treatment of alpha-cyano acetates with N-fluorobenzenesulfonimide as the fluorine source under mild reaction conditions afforded the corresponding alpha-cyano alpha-fluoro acetates in high yields with excellent enantiomeric excesses (85-99% ee). (c) 2005 Elsevier Ltd. All rights reserved.
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