Journal
ORGANIC LETTERS
Volume 7, Issue 9, Pages 1869-1871Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol050559+
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Cu(I) complexes of xanthane-based diphosphines were versatile catalysts for dehydrogenative alcohol silylation, exhibiting high activity and broad substrate scope. Highly selective silylation of 1-decanol over 2-decanol is possible even with a silylating reagent of small steric demand such as HSiMe2Ph or HSiEt3.
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