Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2005, Issue 9, Pages 1715-1726Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200400865
Keywords
decarboxylation; palladium enolates; aldol; allylic alkylation; carroll rearrangement
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Transition metal catalyzed decarboxylation of beta-keto acids and esters provides a convenient route for the regiospecific generation of enolates under neutral conditions. Enolates generated by decarboxylation have been utilized in aldol and Michael additions as well as allylic alkylations. The scope and mechanisms of these transformations are discussed. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
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