Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 70, Issue 9, Pages 3745-3748Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo0500939
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A short and efficient, high-yielding enantioselective total synthesis of the marine natural product (-)-curcuquinone 1 is reported involving a regioselective [3 + 2 + 1]-benzannulation reaction as the key step. Additionally, this strategy allows the isolation of curcuhydroquinone monomethyl ether 9 as an intermediate of the benzannulation reaction and its subsequent further protection toward diversified hydroquinones.
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