Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 38, Issue 5, Pages 423-432Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar040118a
Keywords
-
Categories
Ask authors/readers for more resources
Strategies for the synthesis of polycyclic ethers based on intramolecular allylations are overviewed. The intramolecular condensation of allylic stannanes and aldehydes is a powerful tool for the synthesis of oxepane derivatives. The reaction is successfully applied to the iterative total synthesis of hernibrevetoxin B (2). Further, the intramolecular allylation of alpha-acetoxy ethers provides an efficient method for the convergent synthesis of polycyclic ethers. The usefulness of the latter strategy is demonstrated in the convergent total synthesis of gambierol (4).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available