Journal
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
Volume 9, Issue 5, Pages 380-389Publisher
SPRINGER
DOI: 10.1007/s10008-004-0635-5
Keywords
tribochemistry; cyclic voltammetry; XRD; hexacyanoferrates; solid solutions
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Electrochemical reduction/oxidation cycles of immobilised powder mixtures of KCu[hcc] and KZn[hcf] as well as their mechanical milling lead to the formation of a quaternary solid solution (mixed crystals) with Cu2+ and Zn2+ on the nitrogen coordinated sites and Fe3+ and Co3+ on the carbon coordinated sites. The reaction products were studied by the X-ray diffractometry and voltammetric techniques. The formation of solid solutions of the general formula KCuxZn1-x[hcc](x)[hcf](1-x) is the first example of an electrochemical and mechanochemical reaction leading to mixed hexacyanometalates.
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