Journal
ADVANCED MATERIALS
Volume 17, Issue 9, Pages 1158-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200401549
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Robust self-assembly with very high order is demonstrated by polyisobutylene-block-poly(ethylene oxide) (PIB-PEO) copolymers tailor-made by combining living cationic and anionic polymerization. A cubic micellar phase with long-range order and a glassy phase consisting of deformed spheroids are identified. Application of PIB-PEO in the synthesis of porous titanium oxide yields perfect anatase crystalline films with high regularity (see Figure).
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