Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 232, Issue 1-2, Pages 13-20Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2004.12.037
Keywords
Guerbet reaction; Mg/Al/Cu mixed oxides; heterogeneous catalysts; isobutyl alcohol; methanol; n-propanol; aldol condensation
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The synthesis of isobutyl alcohol ((BuOH)-Bu-i) from methanol (MeOH) and n-propanol (PrOH) through the Guerbet condensation has been studied in batch experiments using bifunctional heterogeneous systems based on a dehydrogenating/hydrogenating metal (Pd, Rh, Ni or Cu) and a basic Mg-Al mixed oxide derived from hydrotalcite-type (HT) precursors. Only copper-based systems showed appreciable performances. In particular, the Cu/Mg/Al mixed oxides catalysts obtained by the co-precipitation method offered the best results in terms of activity and selectivity, thus allowing to reduce pollution problems connected with the up to now adopted copper chromite. These co-precipitated systems were also tested in some preliminary experiments carried out in gas-solid phase in a flow reactor, thus confirming promising application perspectives. (c) 2005 Elsevier B.V. All rights reserved.
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