4.6 Article

A mesoporous Pt/TiO2 nanoarchitecture with catalytic and photocatalytic functions

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 11, Issue 10, Pages 2997-3004

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200401248

Keywords

heterogeneous catalysis; mesoporous materials; photocatalysis; platinum; thin films

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A novel metal/semiconductor nanocomposite with catalytic and photocatalytic functions has been prepared. The new material consists of highly dispersed platinum (Pt) nanoparticles embedded in a cubic mesoporous nanocrystalline anatase (meso-nc-TiO2) thin film. The porous thin film possesses a narrow pore-size distribution and a large surface area. The diameter of the Pt cluster can be controlled to below 5 nm, and the high dispersion of these clusters gives rise to catalytic activity for the oxidation of carbon monoxide, an important reaction for automobile exhaust treatment. This novel ordered mesoporous Pt/TiO2 nanoarchitecture is also a promising photochemical material, as demonstrated by the photo-driven killing of Micrococcus lylae cells on the film.

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