Journal
TETRAHEDRON
Volume 61, Issue 19, Pages 4701-4707Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.01.129
Keywords
optically active arylphosphine; nucleophilic aromatic substitution; P-chiral phosphine
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Optically pure P-chiral (dialkyl)arylphosphine-boranes having high structural diversity were prepared by two- or three-component coupling of fluorobenzenechromium complexes, P-chiral secondary phosphine-boranes, and other nucleophiles. The stereochernical integrity at the P-stereogenic center was completely retained during the SNAr process when the reaction was carried out in THF at low temperature. (c) 2005 Elsevier Ltd. All rights reserved.
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