Journal
TETRAHEDRON LETTERS
Volume 46, Issue 20, Pages 3569-3572Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.03.108
Keywords
ionic liquids (ILs); alkenes; halohydroxylation; halohydrins
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Alkenes undergo smooth bromo- and iodohydroxylation with N-bromo- and N-iodosuccinimides/water, respectively, using the air and moisture stable ionic liquid [bmim]BF4 as a novel recyclable reaction medium in high to quantitative yields. N-Halosuccinimides show enhanced reactivity in ionic liquids thereby reducing the reaction times and improving the yields considerably. (c) 2005 Published by Elsevier Ltd.
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