Journal
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS
Volume 15, Issue 10, Pages 2587-2590Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.bmcl.2005.03.036
Keywords
mycoparasite; lambertellol relatives; biosynthesis; LC-ESIMS
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Lambertellol C (1), a labile biosynthetic congener of lambertellols A and B, was isolated from a fermentation broth of Lambertella sp. 1346 based on the diagnostic isotope patterns in the mass spectrum of a highly labeled sample. The CD spectrum of I indicated that this lambertellol analogue exists as a racemate. The mechanism for this racemization is discussed. (c) 2005 Elsevier Ltd. All rights reserved.
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