Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 26, Issue 10, Pages 825-829Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200500044
Keywords
cyclodextrins; gel-to-sol and sol-to-gel transitions; inclusion chemistry; molecular recognition; poly(acrylic acid)
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By utilizing the interaction of alpha-cyclodextrin (alpha-CD) with dodecyl side chains in polymers of x mol-% dodecyl-modified poly(acrylic acid) (p(AA/C-12(x))), systems that undergo sol-to-gel transitions were successfully constructed. Rheological experiments indicated that addition of alpha-CD to the hydrogel of p(AA/C-12(5)) caused a drastic decrease in the viscosity, while addition of oligo(alpha-CD) to the solution of p(AA/C-12(2)) led to a remarkable increase in the viscosity.
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