4.4 Article

A new dimeric bidentated NHC-Pd(II) complex from trans-cyclohexane-1,2-diamine for Suzuki reaction and Heck reaction

Journal

TETRAHEDRON
Volume 61, Issue 21, Pages 4949-4955

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.03.043

Keywords

trans-cyclohexane-1,2-diamine; Suzuki-Miyaura cross-coupling reaction; Heck reaction; dimeric bidentated NHC-Pd(II) complex; benzimidazolium iodide

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A new dimeric bidentated NHC-Pd(II) complex was synthesized from trans-cyclohexane-1,2-diamine and its structure was characterized by MALDI Mass spectrum. This NHC-Pd(II) complex was fairly effective in Suzuki and Heck reactions to give the products in good to excellent yields in most cases. (c) 2005 Elsevier Ltd. All rights reserved.

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