Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 70, Issue 11, Pages 4498-4501Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo050215x
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The binding of a chiral quaternary ammonium ion to a cyclopeptide containing aromatic amino acid subunits is affected not only by the configuration of the cation but also by the configuration of the chiral counterion. Analysis of the binding equilibria shows that complex formation involves interaction of the whole ion pair with the host indicating that steric requirements of the anion influence complex geometry and stability.
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