4.4 Article

Copper catalyzed oxidation of sulfides to sulfoxides with aqueous hydrogen peroxide

Journal

TETRAHEDRON LETTERS
Volume 46, Issue 22, Pages 3819-3822

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.03.194

Keywords

oxidation; sulfide; hydrogen peroxide; CuSalenH(4); TEMPO

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Copper(II) complex 1 catalyzes the oxidation of sulfides to sulfoxides with 30% H2O2 in high yields. Addition of a catalytic amount of TEMPO to the reaction mixture enhances the conversion and selectivity. Complex I can be recycled without loss of activity. (c) 2005 Elsevier Ltd. All rights reserved.

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