Gas diffusion coefficient of undisturbed peat soils

Determination of the gas diffusion coefficient D-s of peat soils is essential to understand the mechanisms of soil gas transport in peatlands, which have been one of major potential sources of gaseous carbons. In the present study, we aimed at determining the D-s of peat soils for various values of the air-filled porosity a and we tested the validity of the Three-Porosity Model (Moldrup et al. 2004) and the Millington-Quirk model (1961) for predicting the relative gas diffusivity, the ratio of D-s to D-0 the gas diffusion coefficient in free air. Undisturbed peat soil cores were sampled from aerobic layers in the Bibai mire, Hokkaido, Japan. The MQ model reproduced the measured D-s/D-0 curves better than the TPM. The TPM, a predictive model for undisturbed mineral soils, overestimated the D-s/D-0 values for peat soils, implying that in the peat soils the pore pathways were more tortuous than those in the mineral soils. Since the changes in the D-s/D-0 ratios with the a values of a well-decomposed black peat soil tended to be more remarkable than those of other high-moor peat soils, the existence of a positive feedback mechanism was assumed, such that peat soil decomposition itself would increase the soil gas diffusivity and promote soil respiration.