Journal
JOURNAL OF THERMAL SPRAY TECHNOLOGY
Volume 14, Issue 2, Pages 224-230Publisher
ASM INTERNATIONAL
DOI: 10.1361/10599630523782
Keywords
corrosion resistance; gas shroud; high-velocity oxyfuel; molybdenum; stainless steel
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To improve the marine corrosion resistance of stainless steel coatings fabricated by high-velocity oxyfuel (HVOF) spraying with a gas shroud attachment, the molybdenum (Mo) content of stainless steel was increased to form coatings with a chemical composition of Fe balance-18mass%Cr-22mass%Ni-2-8mass%Mo. These coatings were highly dense, with < 0.1 vol.% in porosity, and less oxidized, with 0.5 mass% in oxygen content at most. The corrosion mechanism and resistance of the coatings were investigated by electrochemical measurement, chemical analysis, and statistical processing. The general corrosion resistance of the coatings in 0.5 mol/dm(3) sulfuric acid was improved with increases in Mo content, and the corrosion rate could be decreased to 8.8 x 10(-2) mg/cm(2) per hour (similar to 1 mm/year) at 8 mass% Mo. The pitting corrosion resistance of the coatings in artificial seawater was improved with increases in Mo content and was superior to that of the 316L stainless steel coating. The crevice corrosion resistance of the coatings in artificial seawater was improved and the number of rust spots at 4 mass% Mo was decreased to 38% of that for the 316L coating. Accordingly, Mo is highly effective in improving the corrosion resistance of the stainless steel coatings by HVOF spraying.
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