4.5 Article Proceedings Paper

NMR determination of enantiomeric composition of 1-substituted 3-amino-1,2-dicarba-closo-dodecaboranes using Eu(hfC)3

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 690, Issue 11, Pages 2766-2768

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.01.044

Keywords

3-amino-1,2-dicarba-closo-dodecaboranes; enantiomers; H-1 and C-13 NMR; chiral shift reagent

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Experimental conditions for determination of enantiomeric composition of 1-substituted 3-aminocarboranes by H-1 and C-13 NMR spectroscopy using chiral shift reagent Eu(hfc)(3) have been found. (c) 2005 Elsevier B.V. All rights reserved.

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