Journal
COORDINATION CHEMISTRY REVIEWS
Volume 249, Issue 11-12, Pages 1155-1184Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2004.11.010
Keywords
atom transfer radical polymerization; copper(I); copper(II); structures
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Structural features of copper(I) and copper(II) complexes with bidentate, tridentate and tetradentate nitrogen based ligands commonly used in atom transfer radical polymerization (ATRP) were extensively reviewed and discussed based on several spectroscopic techniques. Complexing ligands included 2,2'-bipyridine (bpy), 4,4'-di(5-nonyl)-2,2'-bipyridine (dNbpy), NNM,APtetramethylethylenediamine (TMEDA), N-propyl(2-pyridyl)methanimine (NPrPMI), 2,2': 6,2 -terpyri dine (tpy), 4,4',4-tris(5-nonyl)- 2,2':6',2-terpyridine (tNtpy), N,N,N',N'',N'''-pentamethyldiethylenetriamine (PMDETA), N,N-bis(2-pyridylmethyl)octylamine (BPMOA), 1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA), tris[2-(dimethylamino)ethyl]amine (Me6TREN), tris[(2-pyridyl)methyl]amine (TPMA) and 1,4,8,1 1-tetraaza-1,4,8,11-tetramethylcyclotetradecane (Me(4)CYCLAM). Additionally, structures of copper(I) and copper(II) complexes with diethylenetriamine (DETA), triethylenetetramine (TETA), N,N-bis(2-pyridylmethyl)amine (BPMA), tris[2-aminoethyl]amine (TREN) and 1,4,8,1 1-tetraazacyclotetradecane (CYCLAM) were discussed. The structures were found to depend on the complexing ligand, solvent and temperature. (c) 2004 Elsevier B.V. All rights reserved.
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