4.8 Article

One-pot synthesis of CdS@Nb2O5 core shell nanostructures with enhanced photocatalytic activity

Journal

APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 152, Issue -, Pages 403-412

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2014.01.025

Keywords

Nanostructured materials; Semiconductor nanoparticles; Photo-oxidation; Environmental process

Funding

  1. CNPq
  2. CAPES
  3. FAPEMIG

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CdS@NbxOy),core-shell nanostructures were used as heterogeneous catalysts for oxidizing organic compounds in aqueous media under ultraviolet light. The core/shell nanocrystals contained two nano-structured semiconductor that enhanced the catalytic properties of the material under UV-Vis irradiation. The developed core/shell nanocrystals displayed significant catalytic activity during the oxidation of organic substrates and may be suitable for degrading organic pollutants in water. The ESI-MS spectrum obtained for methylene blue after exposure to the nanostructured semiconductor nanoparticles revealed a hydroxylation caused by hydroxyl radicals in solution, forming a species at m/z= 301. (c) 2014 Elsevier B.V. All rights reserved.

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