4.8 Article

Esterification of a waste produced from the palm oil industry over 12-tungstophosforic acid supported on kaolin waste and mesoporous materials

Journal

APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 160, Issue -, Pages 122-128

Publisher

ELSEVIER
DOI: 10.1016/j.apcatb.2014.04.039

Keywords

Supported heteropolyacid; Kaolin waste; Mesoporous materials; Esterification

Funding

  1. CAPES
  2. FINEP/SIPI
  3. FAPESPA/Vale
  4. CNPq

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In this work, kaolin waste, MCM-41, MCM-48, and SBA-15 were impregnated with H3PW12O40 (HPW). The obtained solid acid catalysts were characterized by various techniques, such as XRF, XRD, FTIR and N2 adsorption. The surface acidities were measured by acid-base titration of KOH. The catalytic activities of the catalysts in the esterification reaction of a waste produced during the deodorization processes of palm oil (DDPO) were studied. The results revealed that the materials have great potential in promoting heterogeneous acid-catalyzed organic transformations. (C) 2014 Elsevier B.V. All rights reserved.

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