Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 134, Issue -, Pages 198-204Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2013.01.006
Keywords
Synchronical pollutant degradation and H-2 production; In situ Ti3+-doped TiO2 crystal; Mesoporous nanosheets; Exposed (001) facets
Funding
- NSFC [20937003, 21237003, 21261140333]
- Shanghai Key Laboratory of Rare Earth Functional Materials
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In situ Ti3+-doped TiO2 crystal in mesoporous nanosheets with dominant (0 0 I) facets was prepared by supercritical treatment of the precursor obtained from sol-gel hydrolysis of mixed Ti(n-OC4H9)(4) and TiF4. This photocatalyst exhibited high activity in synchronical pollutant degradation and water splitting to produce H-2 under visible light irradiation owing to synergistic promoting effects. On one hand, the narrowed energy band gap resulted from Ti3+-doping and the high surface area enhanced light harvest and reactant adsorption. On the other hand, the high crystallization degree accelerated electron transfer and thus, inhibited photoelectron-hole recombination. Furthermore, the exposed (0 0 1) facets with high surface energy favored the activation of reactant molecules. The photocatalytic degradation of organic pollutants promoted the H-2 production by consuming photogenerated holes, which inhibited their recombination with photoelectrons used for reducing H+ during water splitting. (C) 2013 Elsevier B.V. All rights reserved.
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