Journal
SYNLETT
Volume -, Issue 9, Pages 1450-1452Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2005-868493
Keywords
aldehydes; esters; hydrogen transfer; iridium catalyst; Tishchenko reaction
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Tishchenko reaction of aldehydes in the presence of an amino alcohol-based Ir bifunctional catalyst was developed. The reaction proceeds with 1 mol% of the catalyst and 20-30 mol% of K2CO3 in acetonitrile at room temperature to give the corresponding dimeric esters in good yield.
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