Low-temperature selective catalytic reduction of NOx with NH3 over Mn-containing catalysts

Mn-containing catalysts exhibit a high NOx conversion in selective catalytic reduction (SCR) with NH3. Their high activity (80-100%) covers a broad temperature range (195-600 degrees C). 100% N-2 formation is reached at about 230 degrees C for the catalysts prepared by Mn ion-exchanged in CBV-2314, a MFI zeolite. The catalysts obtained by Mn- or Fe-exchange zeolites are superior for N-2 formation compared to those prepared by wet impregnation of Mn precursors on the gamma-Al2O3 (80%)-TiO2 (20%) catalyst support. Since the Mn catalysts are active for NOx reduction in the intermediate temperature range of diesel engine exhaust mainly, an effort was undertaken in this study to extend this temperature range by promoting Mn with Cu, Ce and Fe oxides. These catalysts with two metals in the active phase were prepared and tested for DeNO(x) activity. All promoted catalysts showed higher formation of N-2 at either low or high temperatures. The Ce/MnCBV-2314 catalyst was more active and stable at high temperatures, close to 600 degrees C, than those containing Fe or Cu oxides. Cu/MnCBV-2314 showed high activity at low temperature. 100% N-2 formation for 2.1Mn/3.8FeCBV ranged from 220 to beyond 450 degrees C. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.