4.8 Article

Clean production of glucose from polysaccharides using a micellar heteropolyacid as a heterogeneous catalyst

Journal

APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 107, Issue 1-2, Pages 104-109

Publisher

ELSEVIER
DOI: 10.1016/j.apcatb.2011.07.002

Keywords

Polyoxometalate; Micellar catalysis, Polysaccharides; Hydrolysis; Glucose

Funding

  1. National Natural Science Foundation of China [20871026]
  2. Fundamental Research Funds for the Central University [10JCXK011]
  3. Jilin Provincial Science and Technology Department

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Hydrolysis of polysaccharides into glucose was performed over a micellar heteropolyacid (HPA) catalyst [C16H33N(CH3)(3)]H2PW12O40 (abbreviated as C16H2PW). This micellar heterogeneous catalyst exhibited high selectivity and activity in the hydrolysis of polysaccharides, such as starch and cellulose. Hydrolysis velocities of starch and cellulose were 0.019 and 0.006 g/h at 120 degrees C and 170 degrees C, respectively. The results demonstrated that C16H2PW is an effective catalyst for the production of glucose and can be reused. (C) 2011 Elsevier B.V. All rights reserved.

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