Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 95, Issue 3-4, Pages 400-407Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2010.01.019
Keywords
Visible light photocatalysis; Charger transfer complex; Organic acids; Dichromate
Funding
- Natural Science Foundation of China [20877031, 20677019]
- Hubei Key Laboratory for Catalysis and Material Science in South-Central University for Nationalities
Ask authors/readers for more resources
Visible light photoreduction of toxic Cr(VI) over TiO2 was achieved through surface modification with small molecular weight organic acids (SOAs) as sacrificial organics. Because neat anatase TiO2 is active only under UV light irradiation (lambda < 387 nm), no photoreduction of Cr(VI) was observed in TiO2 dispersions being irradiated with visible light (lambda > 420 nm). However, when a small amount of colorless SOAs was added into the TiO2 dispersion, a charge-transfer-complex (CTC) was formed between TiO2 and SOA, which was sensitive to visible light irradiation and induced the photo-oxidation of SOA and photoreduction of Cr(VI). It was observed that about 95% of added Cr(VI) (0.2 mmol L-1) was removed in the visible light-illuminated TiO2 (1.0 g L-1) dispersions at pH 3.0 within 2 h by adding 0.2 mmol L-1 tartaric acid as a SOA. The SOA-induced photoreduction of Cr(VI) proceeded via a CTC-mediated path, being governed by chemical structures of sacrificial SOAs. A higher energy of the highest occupied molecular orbital or lower ionization potential of SOAs is favorable to electron transfer within TiO2-SOA complex, thereby accelerating the photoreduction of Cr(VI). The Cr(VI) removal was further enhanced by increasing SOA concentration and/or decreasing solution pH. (C) 2010 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available